Methane & Climate
Methane is emitted during the production and transport of coal, natural gas, and oil. Methane emissions also result from livestock and other agricultural practices and by the decay of organic waste in municipal solid waste landfills.
Ocean Methane Emissions
Methane (CH4) is emitted from a variety of both human-related (anthropogenic) and natural sources. Human-related activities include fossil fuel production, animal husbandry (enteric fermentation in livestock and manure management), rice cultivation, biomass burning, and waste management. These activities release significant quantities of methane to the atmosphere. It is estimated that more than 60 percent of global methane emissions are related to human-related activities (IPCC, 2007:a). Natural sources of methane include wetlands, gas hydrates, permafrost, termites, oceans, freshwater bodies, non-wetland soils, and other sources such as wildfires.
Methane is released by various human activities and contributes to the excess load of greenhouse gases since the pre-industrial era. The growth rate in the atmosphere stalled for a while, but appears to be rising again. The reason for this is not fully understood.
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One issue is how to reduce human-induced methane emissions in the future to slow the growth or (more hopefully) get its concentration to start to fall.
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Another issue is whether global warming will trigger methane releases from natural reservoirs, thus feeding back to drive further warming.
Although methane has been widely implicated as a possible cause of past climate changes, I think the jury is still out as to whether it was ever a major cause.
The main problem is that we don't have any proxies before the ice-core era of past methane changes, and during the ice-core era, the methane changes were too small to be the main cause of the climate changes. The fact that we can't show that methane was a major driver of climate changes in the past doesn't mean we don't know its relative greenhouse effect. This is established securely from the optical properties of the molecule.
There is increasing evidence that the major extinctions of the past several hundreds of millions of years are associated with long lived events following major tectonic disturbances that result in release of greenhouse gases, with associated global warming, ocean anoxia etc.
For example the early Jurassic extinction is associated with events (greenhouse gas induced warming) lasting 200,000 years:
Svensen H et al (2007) Hydrothermal venting of greenhouse gases triggering Early Jurassic global warming Earth Planetary Sci Lett 256 554-566
Abstract: “The climate change in the Toarcian (Early Jurassic) was characterized by a major perturbation of the global carbon cycle. The event lasted for approximately 200,000 years and was manifested by a global warming of similar to 6 degrees C, anoxic conditions in the oceans, and extinction of marine species. The triggering mechanisms for the perturbation and environmental change are however strongly debated. Here, we present evidence for a rapid formation and transport of greenhouse gases from the deep sedimentary reservoirs in the Karoo Basin, South Africa…….”
likewise comprehensive analyses shows a coincidence of major tectonic events, and resulting elevation of greenhouse gas levels, are associated with several of the major extinctions of the last 300 million years. Note that CO2 isn’t the only player. Methane is implicated in several of these events (see especially the PETM below) and sulphurous oxides and their effects on ocean acidity and oxygen content are also implicated:
Wignall P (2005) The link between large igneous province eruptions and mass extinctions Elements 1, 293-297
Abstract: “In the past 300 million years, there has been a near-perfect association between extinction events and the eruption of large igneous provinces, but proving the nature of the causal links is far from resolved. The associated environmental changes often include global warming and the development of widespread oxygen-poor conditions in the oceans. This implicates a role for volcanic CO2 emissions, but other perturbations of the global carbon cycle, such as release of methane from gas hydrate reservoirs or shut-down of photosynthesis in the oceans, are probably required to achieve severe green-house warming. The best links between extinction and eruption are seen in the interval from 300 to 150 Ma. With the exception of the Deccan Trap eruptions (65 Ma), the emplacement of younger volcanic provinces has been generally associated with significant environmental changes but little or no increase in extinction rates above background levels.”
R. J. Twitchett (2006) The palaeoclimatology, palaeoecology and
palaeoenvironmental analysis of mass extinction events
Palaeogeog., Palaeoclimatol., Palaeoecol. 232, 190-213
concluding paragraph: “Mass extinction studies have enjoyed a surge in scientific interest of the past 30 years that shows no sign of abating. Recent areas of particular interest include the palaeoecological study of biotic crises, and analyses of patterns of post-extinction recovery. There is good evidence of rapid climate change affecting all of the major extinction events, while the ability of extraterrestrial impact to cause extinction remains debatable. There is growing evidence that food shortage and suppression of primary productivity, lasting several hundred thousand years, may be a proximate cause of many past extinction events. Selective extinction of suspension feeders and the prevalence of dwarfed organisms in the aftermath are palaeoecological consequences of these changes. The association with rapid global warming shows that study of mass extinction events is not just an esoteric intellectual exercise, but may have implications for the present day.”
Notice that greenhouse environments are associated with the very delayed (millions of years) recovery of biota following these extinctions;
Fraiser ML et al. (2007) Elevated atmospheric CO2 and the delayed biotic recovery from the end-Permian mass extinction Palaeogeog. Palaeoclim. Paleoecol. 252, 164-175
Abstract: Excessive CO2 in the Earth ocean-atmosphere system may have been a significant factor in causing the end-Permian mass extinction. CO2 injected into the atmosphere by the Siberian Traps has been postulated as a major factor leading to the end-Permian mass extinction by facilitating global warming, widespread ocean stratification, and development of anoxic, euxinic and CO2-rich deep waters. A broad incursion of this toxic deep water into the surface ocean may have caused this mass extinction. Although previous studies of the role of excessive CO2 have focused on these “bottom-up” effects emanating from the deep ocean, “top-down” effects of increasing atmosphere CO2 concentrations on ocean-surface waters and biota have not previously been explored. Passive diffusion of atmospheric CO2 into ocean-surface waters decreases the pH and CaCO3 saturation state of seawater, causing a physiological and biocalcification crisis for many marine invertebrates. While both “bottom-up” and “top-down” mechanisms may have contributed to the relatively short-term biotic devastation of the end-Permian mass extinction, such a “top-down” physiological and biocalcification crisis would have had long-term effects and might have contributed to the protracted 5- to 6-million-year-long delay in biotic recovery following this mass extinction. Earth’s Modern marine biota may experience similar “top-down” CO2 stresses if anthropogenic input of atmosphere/ocean CO2 continues to rise.
The lesser extinction associated with the Paleo-Eocene-Thermal Maximum (PETM)55 MYA is probably the best characterized (not surprisingly since it’s the most recent!) example of massive tectonic processes (the opening up of the N. Atlantic as the plates separated) associated with enhanced atmospheric greenhouse gases, ocean acidification etc.:
M. Storey et al. (2007)Paleocene-Eocene Thermal Maximum and the Opening of the Northeast Atlantic Science 316, 587 - 589
abstract: “The Paleocene-Eocene thermal maximum (PETM) has been attributed to a sudden release of carbon dioxide and/or methane. 40Ar/39Ar age determinations show that the Danish Ash-17 deposit, which overlies the PETM by about 450,000 years in the Atlantic, and the Skraenterne Formation Tuff, representing the end of 1 ± 0.5 million years of massive volcanism in East Greenland, are coeval. The relative age of Danish Ash-17 thus places the PETM onset after the beginning of massive flood basalt volcanism at 56.1 ± 0.4 million years ago but within error of the estimated continental breakup time of 55.5 ± 0.3 million years ago, marked by the eruption of mid-ocean ridge basalt–like flows. These correlations support the view that the PETM was triggered by greenhouse gas release during magma interaction with basin-filling carbon-rich sedimentary rocks proximal to the embryonic plate boundary between Greenland and Europe.”
And even the end-Cretaceous extinction (that did for the dinosaurs) seems to have had at least a significant component from massive flood basalt events (that resulted in the Deccan Traps in what is now India). In fact there is increasing evidence that the impact that resulted in the Chicxulub crater in the Yucatan post-dates the onset of the extinction by several 100,000’s of years, and the extinction is associated with global warming (including a sudden contribution from the impact into limestone-rich deposits that vapourized massive amounts of carbonate (limestone) back into CO2):
Keller G (2005) Impacts, volcanism and mass extinction: random coincidence or cause and effect? Austral. J. Earth Sci 52 725-757.
Abstract: “Large impacts are credited with the most devastating mass extinctions in Earth’s history and the Cretaceous - Tertiary (K/T) boundary impact is the strongest and sole direct support for this view. A review of the five largest Phanerozoic mass extinctions provides no support that impacts with craters up to 180 km in diameter caused significant species extinctions. This includes the 170 km-diameter Chicxulub impact crater regarded as 0.3 million years older than the K/T mass extinction. A second, larger impact event may have been the ultimate cause of this mass extinction, as suggested by a global iridium anomaly at the K/T boundary, but no crater has been found to date. The current crater database suggests that multiple impacts, for example comet showers, were the norm, rather than the exception, during the Late Eocene, K/T transition, latest Triassic and the Devonian-Carboniferous transition, but did not cause significant species extinctions. Whether multiple impacts substantially contributed to greenhouse worming and associated environmental stresses is yet to be demonstrated. From the current database, it must be concluded that no known Phanerozoic impacts, including the Chicxulub impact (but excluding the K/T impact) caused mass extinctions or even significant. species extinctions. The K/T mass extinction may have been caused by the coincidence of a very large impact ( > 250 km) upon a highly stressed biotic environment as a result of volcanism. The consistent association of large magmatic provinces (large igneous provinces and continental flood-basalt provinces) with all but one (end-Ordovician) of the five major Phanerozoic mass extinctions suggests that volcanism played a major role. Faunal and geochemical evidence from the end-Permian, end-Devonian, end-Cretaceous and Triassic/Jurassic transition suggests that the biotic stress was due to a lethal combination of tectonically induced hydrothermal and volcanic processes, leading to eutrophication in the oceans, global warming, sea-level transgression and ocean anoxia. It must be concluded that major magmatic events and their long-term environmental consequences are major contributors, though not the sole causes of mass extinctions. Sudden mass extinctions, such as at the K/T boundary, may require the coincidence of major volcanism and a very large Impact.”
Beerling DJ et al. (2002) An atmospheric pCO(2) reconstruction across the Cretaceous-Tertiary boundary from leaf megafossils Proc. Natl. Acad. Sci. USA 99 (12): 7836-7840
Abstract: “The end-Cretaceous mass extinctions, 65 million years ago, profoundly influenced the course of biotic evolution. These extinctions coincided with a major extraterrestrial impact event and massive volcanism in India. Determining the relative importance of each event as a driver of environmental and biotic change across the Cretaceous-Tertiary boundary (KTB) crucially depends on constraining the mass of CO2 injected into the atmospheric carbon reservoir. Using the inverse relationship between atmospheric CO2 and the stomatal index of land plant leaves, we reconstruct Late Cretaceous-Early Tertiary atmospheric CO2 concentration (pCO(2)) levels with special emphasis on providing a pCO(2) estimate directly above the KTB. Our record shows stable Late Cretaceous/ Early Tertiary background pCO(2) levels of 350-500 ppm by volume, but with a marked increase to at least 2,300 ppm by volume within 10,000 years of the KTB. Numerical simulations with a global biogeochemical carbon cycle model indicate that CO2 outgassing during the eruption of the Deccan Trap basalts fails to fully account for the inferred pCO(2) increase. Instead, we calculate that the postboundary pCO(2) rise is most consistent with the instantaneous transfer of approximate to 4,600 Gt C from the lithic to the atmospheric reservoir by a large extraterrestrial bolide impact. A resultant climatic forcing of +12 W(.)m(-2) would have been sufficient to warm the Earth’s surface by approximate to7.5degreesC, in the absence of counter forcing by sulfate aerosols. This finding reinforces previous evidence for major climatic warming after the KTB impact and implies that severe and abrupt global warming during the earliest Paleocene was an important factor in biotic extinction at the KTB.”
